A Highly Active Manganese Catalyst for Enantioselective Ketone and Ester Hydrogenation
Top Cited Papers
- 20 April 2017
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition
- Vol. 56 (21) , 5825-5828
Abstract
A new hydrogenation catalyst based on a manganese complex of a chiral P,N,N ligand has been found to be especially active for the hydrogenation of esters down to 0.1 mol % catalyst loading, and gives up to 97 % ee in the hydrogenation of pro‐chiral deactivated ketones at 30–50 °C.Keywords
Funding Information
- Engineering and Physical Sciences Research Council
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