A New Hexaferrocene Complex with a [M3(μ3-O)]7+Core
- 1 December 2006
- journal article
- research article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 45 (26) , 10443-10445
Abstract
The new hexaferrocene complex 1 has been synthesized and characterized by X-ray diffraction. Its magnetization data were fitted to a detailed theoretical model that considers nonequivalent exchange parameters between Fe ions to yield the magnetic exchange coupling values of J1/kB = −31.5 K and J2/kB = −25.8 K. Moreover, the cyclic voltammogram of complex 1 confirmed its redox activity associated with the presence of ferrocene units, with very small or negligible electronic interactions between them.Keywords
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