Suzuki–Miyaura Cross‐Coupling Reaction Catalyzed by PEPPSI‐Type 1,4‐Di(2,6‐diisopropylphenyl)‐1,2,3‐triazol‐5‐ylidene (tzIPr) Palladium Complex
Authors:
- 11 October 2012
- journal article
- research article
- Published by Wiley in European Journal of Organic Chemistry
- Vol. 2012 (33) , 6630-6635
Abstract
A 1,4‐di(2,6‐diisopropylphenyl)‐1,2,3‐triazol‐5‐ylidene (tzIPr)‐based PEPPSI‐type palladium complex was developed as an excellent precatalyst for the Suzuki–Miyaura cross‐coupling reaction. The complex showed high activity under mild conditions for the cross‐coupling reactions between various types of aryl chlorides and aryl boronic acids regardless of the steric and electronic nature of the substrates.Keywords
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