Chiral N-Heterocyclic Carbene−Pd(0)-Catalyzed Asymmetric Diamination of Conjugated Dienes and Triene
Authors:
- 21 December 2007
- journal article
- research article
- Published by American Chemical Society (ACS) in The Journal of Organic Chemistry
- Vol. 73 (2) , 749-751
Abstract
Studies show that a variety of conjugated dienes and triene can be enantioselectively diaminated using di-tert-butyldiaziridinone as nitrogen source and chiral N-heterocyclic carbene−Pd(0) complex as catalyst in good enantioselectivity (62−91% ee) with high regio- and diastereoselectivity.Keywords
This publication has 24 references indexed in Scilit:
- Enantioselective copper catalysed 1,4-conjugate addition reactions using chiral N-heterocyclic carbenesJournal of Organometallic Chemistry, 2005
- Chiral N-heterocyclic carbenes as stereodirecting ligands in asymmetric catalysisChemical Society Reviews, 2004
- γ-Selective allylic substitution reaction with Grignard reagents catalyzed by copper N -heterocyclic carbene complexes and its application to enantioselective synthesisTetrahedron Letters, 2004
- Synthesis of New Chiral N-Heterocyclic Carbene−Imine Ligands and Their Application to an Asymmetric Allylic Alkylation ReactionOrganometallics, 2003
- Palladium Catalysts for Aerobic Oxidative Kinetic Resolution of Secondary Alcohols Based on Mechanistic InsightOrganic Letters, 2002
- N-Heterocyclic Carbenes: A New Concept in Organometallic CatalysisAngewandte Chemie International Edition, 2002
- Enantioselective Ruthenium-Catalyzed Ring-Closing MetathesisOrganic Letters, 2001
- Chiral Imidazolylidine Ligands for Asymmetric Hydrogenation of Aryl AlkenesJournal of the American Chemical Society, 2001
- Improved Catalysts for the Palladium-Catalyzed Synthesis of Oxindoles by Amide α-Arylation. Rate Acceleration, Use of Aryl Chloride Substrates, and a New Carbene Ligand for Asymmetric TransformationsThe Journal of Organic Chemistry, 2001
- First Chelated Chiral N-Heterocyclic Bis-Carbene ComplexesOrganic Letters, 2000