Generation and Characterization of the First Persistent Platinum(I)‐Centered Radical
- 6 June 2018
- journal article
- research article
- Published by Wiley in Angewandte Chemie
- Vol. 130 (27) , 8407-8411
Abstract
The first persistent platinum(I)‐centered radical was generated by homolytic cleavage of a Pt−HgSiR3bond of a mercury‐substituted platinum(II) complex. The PtIradical was characterized by EPR spectroscopy, chemical trapping experiments, and density functional theory (DFT) calculations.Keywords
Funding Information
- Israel Science Foundation
- Minerva Foundation
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