Csp3–F bond activation by nucleophilic attack of the {Pt2S2} core assisted by non-covalent interactions
- 29 April 2008
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 27,p. 3130-3132
Abstract
The high nucleophilicity of the sulfur atoms in [Pt2(dppp)2(μ-S)2] triggers a C–F activation process in 1,3-difluoro-2-propanol that leads to the [Pt2(dppp)2(μ-S)(μ-SCH2CH(OH)CH2F]F product through a SN2 mechanism, where the O–H⋯F hydrogen bond established from the alcohol group of the organic substrate is essential for assisting the departure of the fluoride anion.Keywords
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