Transition-metal-free phosphorylation of polyfluoroarenes with P(O)H compounds

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Abstract
A base-promoted C–P(O) bond formation method has been developed for the phosphorylation of polyfluoroarenes through selective C–F bond cleavage.
Funding Information
  • Natural Science Foundation of Hunan Province (2022JJ20055, 2023JJ60110)
  • Fundamental Research Funds for the Central Universities

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