Sterically encumbered charge-compensated carbaboranes: Synthesis and reactivity molecular structures of 7-Ph-11-SMe2-7,8-nido-C2B9H10 and 1-Ph-3,3-(CO)2-7-SMe2-3,1,2-closo-RhC2B9H8
Authors:
- Georgina M. RosairGeorgina M. Rosair
- Alan J. WelchAlan J. Welch
- Andrew S. WellerAndrew S. Weller
- Stephan K. ZahnSZStephan K. Zahn
- 30 May 1997
- journal article
- Published by Elsevier in Journal of Organometallic Chemistry
- Vol. 536-537, 299-308
Abstract
No abstract availableKeywords
This publication has 20 references indexed in Scilit:
- Reaction of nido-7,8-C2B9H13 with pentacarbonyl(methyl)manganese: Crystal structure of the charge-compensated complex [Mn(CO)3{η5-7,8-C2B9H10-10-O(CH2)4}]Polyhedron, 1996
- Synthesis, characterisation and molecular structures of the closo and pseudocloso heptamethylindenyl carbarhodaboranes 1-Ph-3-(η-C9Me7)-3,1,2-closo-RhC2B9H10and 1,2-Ph2-3-(η-C9Me7)-3,1,2-pseudocloso-RhC2B9H9. Experimental assignment of the11B NMR spectrum of a pseudocloso carbametallaboraneJ. Chem. Soc., Dalton Trans., 1996
- Synthesis and characterisation of pseudocloso iridium and ruthenium diphenyl carbaboranes. Molecular structures of 1,2-Ph 2 -3-(η-C 6 H 6 )-3,1,2-pseudocloso-RuC 2 B 9 H 9 and 1,2-Ph 2 -3-(cym)-3,1,2-pseudocloso-RuC 2 B 9 H 9 (cym =p-cymene) and individual gauge for localised orbitals calculations on carbametallaboranesJ. Chem. Soc., Dalton Trans., 1996
- Mixed Sandwich Carborane/Thiamacrocycle Compounds. Synthesis and Characterization of 1-Ph-3,3,3-[9]aneS3-κ3-S,S‘,S‘‘-3,1,2-closo-RuC2B9H10 and 1,2-Ph2-3,3,3-[9]aneS3-κ3-S,S‘,S‘‘-3,1,2-pseudocloso-RuC2B9H9,Inorganic Chemistry, 1996
- Diastereomers of the carborane sandwich complex commo-[3,3-Fe{4-(Me2S)-1,2-C2B9H10}2]; crystal structure of meso-[Fe(C2B9H10SMe2)2]Journal of Organometallic Chemistry, 1995
- Synthesis and characterisation of the mixed-sandwich complex closo-[3-(η-C5Me5)Fe-4-Me2S-1,2-C2B9H10] and its charge-transfer salts; crystal structure of [Fe(η-C5Me5)-(C2B9H10SMe2)]+[ddq]˙–·CH2Cl2(ddq = 2,3-dichloro-5,6-dicyano-p-benzoquinone)J. Chem. Soc., Dalton Trans., 1995
- Sterically-induced low temperatur polyhedral rearrangements of carbaplatinaboranes: Synthesis and crystal structures of 1-Ph-3,3-(PMe2Ph)2-3,1,2-PtC2B9H10, 1-Ph-3,3-(PMe2Ph)2-3,1,11-PtC2B9H10, 11-Ph-3,3-(PMe2Ph)2-3,1,11-PtC2B9H10 and 1,11-Ph2-3,3-(PMe2Ph)2-3,1,11-PtC2B9H9Journal of Organometallic Chemistry, 1993
- The chemistry of monoanionic carbaborane ligands. Synthesis and structure of compounds with carbonyl and cycloocta-1,5-diene ligands additionally bound to metal atoms, including a cationic carbametallaboraneJ. Chem. Soc., Dalton Trans., 1993
- The chemistry of monoanionic carbaborane ligands. Synthesis, and molecular and electronic structure of [3,3,3-(CO)3-4-SMe2-3,1,2-MnC2B9H10], and order-of-magnitude improved structure of (η-C5H5)Mn(CO)3Journal of Organometallic Chemistry, 1990
- Preparation and characterization of the (3)-1,2- and (3)-1,7-dicarbadodecahydroundecaborate(-1) ionsJournal of the American Chemical Society, 1968