Low‐Dimensional Nanomaterials Based on Small Organic Molecules: Preparation and Optoelectronic Properties
Authors:
- 4 August 2008
- journal article
- review article
- Published by Wiley in Advanced Materials
- Vol. 20 (15) , 2859-2876
Abstract
This article presents a comprehensive review of recent progress of research dedicated to low‐dimensional nanomaterials constructed from functional low‐molecular‐weight organic compounds, whose optoelectronic properties are fundamentally different from those of their inorganic counterparts. After introducing the development of inorganic and organic macromolecular nanomaterials, we begin with a general review of the construction strategies for achieving both zero‐dimensional (0D) and one‐dimensional (1D) nanostructures from small organic functional molecules. We then provide an overview of the unique optoelectronic properties induced by molecular aggregation in the nanostructures. Special emphasis is put on the luminescent properties that are different from those of the corresponding bulk materials, such as aggregation‐induced enhanced emission, fluorescence narrowing, multicolor emission, and tunable and switchable emissions from doped nanostructures. We conclude with a summary and our personal view of the direction of future development of organic opto‐functional nanomaterials and devices.Keywords
This publication has 207 references indexed in Scilit:
- Single‐Crystal Organic Nanowires of Copper–Tetracyanoquinodimethane: Synthesis, Patterning, Characterization, and Device ApplicationsAngewandte Chemie International Edition, 2007
- A hierarchical self-assembly of 4,5-diphenylimidazole on copperColloids and Surfaces A: Physicochemical and Engineering Aspects, 2006
- Particle‐Size Control and Patterning of a Charge‐Transfer Complex for NanoelectronicsAdvanced Materials, 2005
- Novel mesostructures of a stilbazolium-like dye based on multistage associationColloids and Surfaces A: Physicochemical and Engineering Aspects, 2005
- Electronic conductance through organic nanowiresPhysical Review B, 2005
- Isolated hexaphenyl nanofibers as optical waveguidesApplied Physics Letters, 2003
- Fabrication of organic nanocrystals using microwave irradiation and their optical propertiesOptical Materials, 2003
- Scaling of Fluorescence Stokes Shift and Superradiance Coherence Size in Disordered Molecular AggregatesThe Journal of Physical Chemistry A, 1999
- Organized Semiconducting Nanostructures from Conjugated Block Copolymer Self-AssemblyChemistry of Materials, 1998
- Vibronic charge-transfer excitons: Possible nature of the unusual properties of virtual perovskitelike ferroelectricsPhysics of the Solid State, 1998