Properties of Lattice and Continuum van der Waals Fluids at the Critical Point
Authors:
- 7 January 1966
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 141 (1) , 198-199
Abstract
A suggestion by Fisher that the specific heats of lattice gases and continuum fluids near the critical point be compared on the basis of specific heat measured in units of the volume per particle at close packing is examined for systems with hard cores and long-range attractive potentials (van der Waals systems). It is found that the discontinuity at the critical point in the specific heat so defined is indeed similar for lattice gases and continuum systems in one, two, and three dimensions, while the critical density varies widely. No explanation is offered. Numerical values of other critical constants are also given.Keywords
This publication has 4 references indexed in Scilit:
- Specific Heat of a Gas Near the Critical PointPhysical Review B, 1964
- Calculation of the pair correlation functionPhysica, 1964
- Fifth and Sixth Virial Coefficients for Hard Spheres and Hard DisksThe Journal of Chemical Physics, 1964
- On the van der Waals Theory of the Vapor-Liquid Equilibrium. I. Discussion of a One-Dimensional ModelJournal of Mathematical Physics, 1963