A Nitrido Salt Reagent of Titanium
Authors:
- 23 May 2014
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 136 (23) , 8197-8200
Abstract
Deprotonation of the parent titanium imido (tBunacnac)Ti≡NH(Ntolyl2) (tBunacnac– = [ArNCtBu]2CH; Ar = 2,6-iPr2C6H3) with KCH2Ph forms a rare example of a molecular titanium nitride as a dimer, {[K][(tBunacnac)Ti≡N(Ntolyl2)]}2. From the parent imido or nitride salt, the corresponding aluminylimido–etherate adduct, (tBunacnac)Ti≡N[AlMe2(OEt2)](Ntolyl2), can be isolated and structurally characterized. The parent imido is also a source for the related borylimido, (tBunacnac)Ti═NBEt2(Ntolyl2).Keywords
Funding Information
- U.S. Department of Energy (DE-FG02-07ER15893)
- Natural Sciences and Engineering Research Council of Canada (NA)
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