Synthesis, electronic nature, and reactivity of selected silylene carbonyl complexes
Open Access
- 11 May 2022
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Dalton Transactions
- Vol. 51 (21) , 8249-8257
Abstract
We report on the syntheses and single crystal X-ray structures of rare room-temperature stable silylene carbonyl complexes [L(X)Ga]2Si-CO, the influence of the substituent X on their electronic nature and their promising potential in NH3 activation.Keywords
Funding Information
- University of Duisburg-Essen
- Justus Liebig University Giessen
- Alexander von Humboldt-Stiftung/Foundation
- Deutsche Forschungsgemeinschaft (SCHU 1069/26-1)
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