Selective hydrogenation of unsaturated aldehydes over Pt nanoparticles promoted by the cooperation of steric and electronic effects
- 2 January 2018
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- Vol. 54 (8) , 908-911
Abstract
The selective hydrogenation of α,β-unsaturated aldehydes to unsaturated alcohols can reach high selectivity and activity at room temperature using Pt nanoparticles immobilized on a non-porous Al 2 O 3 support stabilized by aspartic acid.Keywords
Funding Information
- Chinese Academy of Sciences (QYZDY-SSW-SLH013)
- National Natural Science Foundation of China (21603235)
This publication has 44 references indexed in Scilit:
- Prominent Electronic and Geometric Modifications of Palladium Nanoparticles by Polymer Stabilizers for Hydrogen Production under Ambient ConditionsAngewandte Chemie International Edition, 2012
- Mechanistic Insights on the Hydrogenation of α,β-Unsaturated Ketones and Aldehydes to Unsaturated Alcohols over Metal CatalystsACS Catalysis, 2012
- Turnover Numbers and Soluble Metal NanoparticlesChemCatChem, 2011
- Particle size effects for carbon nanofiber supported platinum and ruthenium catalysts for the selective hydrogenation of cinnamaldehydeApplied Catalysis A: General, 2008
- Hydrogenation Processes in the Synthesis of Perfumery IngredientsAccounts of Chemical Research, 2007
- Bisphenols from Furfurals by Organocatalysis and Gold CatalysisSynlett, 2007
- Unusual Non-Bulk Properties in Nanoscale Materials: Thermal Metal−Metal Bond Contraction of γ-Alumina-Supported Pt CatalystsJournal of the American Chemical Society, 2006
- Asymmetric Rhodium‐Catalyzed Hydrogenation Meets Gold‐Catalyzed Cyclization: Enantioselective Synthesis of 8‐HydroxytetrahydroisoquinolinesChemistry – A European Journal, 2006
- Behaviour of palladium and ruthenium catalysts on alumina and silica prepared by gas and liquid phase deposition in cinnamaldehyde hydrogenationApplied Catalysis A: General, 2002
- An X-ray photoelectron spectroscopic study of the interaction of oxygen and nitric oxide with aluminiumProceedings of the Royal Society of London. A. Mathematical and Physical Sciences, 1978