7-Step total synthesis of (+)-EBC-329: Photoisomerisation reveals new seco-casbane family member
- 18 August 2017
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Organic & Biomolecular Chemistry
- Vol. 15 (34) , 7102-7105
Abstract
The first seco-casbane, EBC-329, isolated from the Australian rainforest, was synthesised from (+)-2-carene in seven steps. This endeavour not only established the absolute stereochemical assignment as (8R,9S)-EBC-329, but also identified, via photoisomerisation, a new seco-casbane family member.Keywords
Funding Information
- University of Queensland
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