Hydroboration of isocyanides with diisopropylaminoborane: general access to ambiphilic boron-based glycine isosteres
Open Access
- 25 August 2026
- journal article
- Published by Royal Society of Chemistry (RSC) in Organic Chemistry Frontiers
- Vol. 13 (17) , 5777-5786
Abstract
We report a straightforward and catalyst-free synthetic methodology for accessing α-aminoboron compounds incorporating the N–CH 2 –B motif through the double hydroboration of various isocyanides using diisopropylaminoborane (DIAB).Keywords
Funding Information
- Centre National de la Recherche Scientifique
- Agence Nationale de la Recherche (p18018)
- Agence Nationale de la Recherche (p20038)
- Institut de chimie (SILVA)
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