Remarkable Near-Infrared Temperature Sensing Properties of Y3Ga5O12:Cr3+ and Y3Ga5O12:Cr3+/Yb3+ Nanotubes Fabricated via a Single-Needle Electrospinning Technique

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Abstract
For the first time, nanotubes of Y3Ga5O12:Cr3+ (referred to as YGO:Cr3+) and Y3Ga5O12:Cr3+/Yb3+ (referred to as YGO:Cr3+/Yb3+) were produced via a single-needle electrospinning method. The nanotubes of YGO:Cr3+ and YGO:Cr3+/Yb3+ have outer diameters between 190 and 210 nm, whereas the inner diameter ranges between 70 and 80 nm, and the wall thickness ranges from 50 to 60 nm. The temperature sensitivity of YGO:0.02Cr3+ nanotubes was examined by studying how the Cr3+ lifetime changes with temperature. In the temperature range of 303 to 723 K, the peak values of Sa and Sr were 0.274 and 0.0067 K-1, respectively. Temperature sensing properties of YGO:0.02Cr3+/yYb3+ (y = 0.01, 0.02, and 0.05) nanotubes were evaluated via the FIR technique utilizing nonthermally coupled energy levels. The I970/I708 in the YGO:0.05Cr3+/0.01Yb3+ nanotubes displayed a maximal Sr value of 0.013 K-1 at 633 K, which exceeds that of other Cr3+-doped NIR phosphors previously reported and is promising for high-temperature measurements.
Funding Information
  • Fundamental Research Funds for the Central Universities (3132023519)
  • National Natural Science Foundation of China (11704056, 11774042, 12274049)

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