Rigorous treatment of polytopal rearrangements reveal surprising complexity of stereoisomerism configuration landscapes
Open Access
- 18 March 2025
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Science
- Vol. 16 (16) , 6705-6719
Abstract
Previously we posited that a systematic and general description of stereoisomerism could be based upon the principles of the polytopal rearrangement model.Keywords
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Funding Information
- Department of Education, Australian Government (SC1999)
- Australian Research Council (DP0666378, DP0773847)
- National Computational Infrastructure Australia (NCMAS d63)
This publication has 40 references indexed in Scilit:
- “Polytopal Rearrangement Model of Stereoisomerization” and Its Potential as the Basis for a Systematic Model of All StereoisomerismACS Organic & Inorganic Au, 2024
- Umbrella inversion of ammonia reduxPhysical Chemistry Chemical Physics, 2021
- Describing Polytopal Rearrangements of Fluxional Molecules with Curvilinear Coordinates Derived from Normal Vibrational Modes: A Conceptual Extension of Cremer–Pople Puckering CoordinatesJournal of Chemical Theory and Computation, 2020
- A new fundamental type of conformational isomerismNature Chemistry, 2018
- Revisiting the polytopal rearrangements in penta-coordinate d 7 -metallocomplexes: modified Berry pseudorotation, octahedral switch, and butterfly isomerizationChemical Science, 2017
- Stereomutation of Pentavalent Compounds: Validating the Berry Pseudorotation, Redressing Ugi’s Turnstile Rotation, and Revealing the Two- and Three-Arm TurnstilesJournal of the American Chemical Society, 2010
- Minimal Distortion Pathways in Polyhedral RearrangementsJournal of the American Chemical Society, 2004
- Mapping the Stereochemistry and Symmetry of Tetracoordinate Transition‐Metal ComplexesChemistry – A European Journal, 2003
- The case of medium-dependent dual mechanisms for photoisomerization: One-bond-flip and Hula-TwistProceedings of the National Academy of Sciences, 2000
- Effects of bond‐angle inversion on the statistical properties of poly(dimethylsiloxane)Journal of Polymer Science Part B: Polymer Physics, 1988