Generation and Intramolecular Reactivity of Acyl Radicals from Alkynylthiol Esters under Reducing Tin-Free Conditions
- 18 March 2003
- journal article
- letter
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 5 (8) , 1313-1316
Abstract
The radical chain reaction of benzenethiol with alkynylthiol esters provides a new, valuable protocol for the tin-free generation of acyl radicals that arise from intramolecular substitution at sulfur by the initial sulfanylvinyl radicals.Keywords
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