Rhodium-Catalyzed Si-F Exchange Reaction between Fluorobenzenes and a Disilane. Catalytic Reaction Involving Cleavage of C-F Bonds
Authors:
- 1 February 1998
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 27 (2) , 157-158
Abstract
The reaction of functionalized fluorobenzenes, such as fluoroacetophenones and (fluorophenyl)oxazolines, with Me3SiSiMe3 in the presence of a catalytic amount of a rhodium complex results in a site-selective Si-F exchange to give ortho-(trimethylsilyl)fluorobenzenes. The reaction involves cleavage of C-F bonds.Keywords
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