The mechanism of activation of amidobenzylidene ruthenium chelates – latent catalysts of olefin metathesis
- 9 January 2017
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Dalton Transactions
- Vol. 46 (4) , 1277-1282
Abstract
Amidobenzylidene ruthenium chelates – latent catalysts of olefin metathesis can be easily activated by the addition of Brønsted or Lewis acids. Their activation in the presence of hydrogen chloride involves the formation of catalytically active trans-dichloro carbamatobenzylidene ruthenium chelates.Keywords
Funding Information
- Narodowe Centrum Nauki (No. UMO-2011/03/B/ST5/01047, Sonata Bis No. 2012/05/E/ST5/03792)
This publication has 26 references indexed in Scilit:
- Ruthenium nitronate complexes as tunable catalysts for olefin metathesis and other transformationsChemical Communications, 2013
- Ruthenium–Amido Complexes: Synthesis, Structure, and Catalytic Activity in Olefin MetathesisChemistry – A European Journal, 2012
- Chelating alkylidene ligands as pacifiers for ruthenium catalysed olefinmetathesisDalton Transactions, 2011
- ADMET: Metathesis polycondensationJournal of Polymer Science Part A: Polymer Chemistry, 2011
- Recent advances in ring-opening metathesis polymerization, and application to synthesis of functional materialsPolymer Journal, 2010
- Predicting the Cis−Trans Dichloro Configuration of Group 15−16 Chelated Ruthenium Olefin Metathesis Complexes: A DFT and Experimental StudyInorganic Chemistry, 2009
- Latent olefin metathesis catalystsChemical Society Reviews, 2009
- A Dormant Ruthenium Catalyst Bearing a Chelating Carboxylate Ligand: In Situ Activation and Application in Metathesis ReactionsAngewandte Chemie, 2007
- Carbene transposition involving double dehydrogenation of an sp3 carbonChemical Communications, 2001
- Well-Defined Ruthenium Olefin Metathesis Catalysts: Mechanism and ActivityJournal of the American Chemical Society, 1997