Preparation of poly(phenylene vinylene) from cycloalkylene sulfonium salt monomers and polymers
Authors:
- 1 November 1988
- journal article
- research article
- Published by Wiley in Journal of Polymer Science Part A: Polymer Chemistry
- Vol. 26 (12) , 3241-3249
Abstract
Two new types of p‐xylene bis‐sulfonium chloride monomers were prepared from cycloalkylene sulfides. The polymerization characteristics of these monomers to form poly(p‐xylene sulfonium chlorides), and the thermal elimination reactions of their polymers to poly(p‐phenylene vinylene), were compared with those of two monomers prepared from dialkyl sulfides. The cycloalkylene sulfonium chloride monomer polymerized to higher yields and to higher molecular weight polymers, which showed more efficient elimination reactions.Keywords
This publication has 8 references indexed in Scilit:
- Mechanism of thermal generation of poly(p-phenylene vinylene) from poly(p-xylene-α-dimethylsulphonium halides)Polymer, 1987
- Molecular orientation and conductivity in highly drawn poly(p-phenylene vinylene)Synthetic Metals, 1987
- Structure investigation of poly(p‐phenylene vinylene)Journal of Polymer Science Part B: Polymer Physics, 1986
- Synthesis and electrical conductivity of AsF5-doped poly(arylene vinylenes)Polymer Bulletin, 1986
- Highly Conducting Poly(P-Phenylene Vinylene) Prepared From Sulfonium SaltMolecular Crystals and Liquid Crystals, 1985
- High Molecular Weight Polyphenylene VinyleneMolecular Crystals and Liquid Crystals, 1985
- The polymerization of xylylene bisdialkyl sulfonium saltsJournal of Polymer Science: Polymer Symposia, 1985
- Conductivity anisotropy in oriented poly(p-Phenylene vinylene)Polymer Bulletin, 1984