α-Fe2O3 Nanoparticle-Loaded Carbon Nanofibers as Stable and High-Capacity Anodes for Rechargeable Lithium-Ion Batteries
- 23 April 2012
- journal article
- research article
- Published by American Chemical Society (ACS) in ACS Applied Materials & Interfaces
- Vol. 4 (5) , 2672-2679
Abstract
α-Fe2O3 nanoparticle-loaded carbon nanofiber composites were fabricated via electrospinning FeCl3·6H2O salt-polyacrylonitrile precursors in N,N-dimethylformamide solvent and the subsequent carbonization in inert gas. Scanning electron microscopy, transmission electron microscopy, energy dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, X-ray diffraction, and elemental analysis were used to study the morphology and composition of α-Fe2O3-carbon nanofiber composites. It was indicated that α-Fe2O3 nanoparticles with an average size of about 20 nm have a homogeneous dispersion along the carbon nanofiber surface. The resultant α-Fe2O3-carbon nanofiber composites were used directly as the anode material in rechargeable lithium half cells, and their electrochemical performance was evaluated. The results indicated that these α-Fe2O3-carbon nanofiber composites have high reversible capacity, good capacity retention, and acceptable rate capability when used as anode materials for rechargeable lithium-ion batteries.Keywords
This publication has 50 references indexed in Scilit:
- DNA-directed growth of FePO4 nanostructures on carbon nanotubes to achieve nearly 100% theoretical capacity for lithium-ion batteriesEnergy & Environmental Science, 2012
- Graphene/Si multilayer structure anodes for advanced half and full lithium-ion cellsNano Energy, 2012
- Graphene Oxide as a Sulfur Immobilizer in High Performance Lithium/Sulfur CellsJournal of the American Chemical Society, 2011
- A Hierarchically Nanostructured Composite of MnO2/Conjugated Polymer/Graphene for High‐Performance Lithium Ion BatteriesAdvanced Energy Materials, 2011
- Electrospun Nanofiber-Based Anodes, Cathodes, and Separators for Advanced Lithium-Ion BatteriesPolymer Reviews, 2011
- Recent developments in nanostructured anode materials for rechargeable lithium-ion batteriesEnergy & Environmental Science, 2011
- Nanostructured carbon-based electrodes: bridging the gap between thin-film lithium-ion batteries and electrochemical capacitorsEnergy & Environmental Science, 2011
- Nano active materials for lithium-ion batteriesNanoscale, 2010
- Oriented Nanostructures for Energy Conversion and StorageChemSusChem, 2008
- Nanomaterials for Rechargeable Lithium BatteriesAngewandte Chemie International Edition, 2008