NO2adducts of C60: synthesis of polynitro–polyhydroxy fullerenes
Authors:
- Subrata RoySRSubrata Roy
- Sabyasachi SarkarSabyasachi Sarkar
- 1 January 1994
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 275-276
Abstract
C60 is nitrated by multiple addition of NO2; the product isomerizes partly to the nitrito form with subsequent hydrolysis by atmospheric moisture to yield nitrofullerols consisting of 6–8 nitro and 7–12 hydroxy groups per C60.Keywords
This publication has 17 references indexed in Scilit:
- The chemistry of fullerenesNature, 1993
- Synthesis and Single-Crystal X-ray Structure of a Highly Symmetrical C 60 Derivative, C 60 Br 24Science, 1992
- C60‐Fullerene—A Playground for Chemical Manipulations on Curved Surfaces and in Cavities**Angewandte Chemie International Edition, 1992
- Chlorination and bromination of fullerenes. Nucleophilic methoxylation of polychlorofullerenes and their aluminum trichloride catalyzed Friedel-Crafts reaction with aromatics to polyarylfullerenesJournal of the American Chemical Society, 1991
- Polyarenefullerenes, C60(H-Ar)n, obtained by acid-catalyzed fullerenation of aromaticsJournal of the American Chemical Society, 1991
- Fluorinated fullerenesJournal of the American Chemical Society, 1991
- Fluorination of buckminsterfullereneJournal of the Chemical Society, Chemical Communications, 1991
- Efficient production of C60 (buckminsterfullerene), C60H36, and the solvated buckide ionThe Journal of Physical Chemistry, 1990
- Solid C60: a new form of carbonNature, 1990
- Isolation, separation and characterisation of the fullerenes C60 and C70: the third form of carbonJournal of the Chemical Society, Chemical Communications, 1990