Synthesis, chain conformation and crystal structure of poly(norbornadiene) having repeating 3,5-enchained nortricyclene units
Authors:
- Claudio De RosaClaudio De Rosa
- Anna MalafronteAMAnna Malafronte
- Finizia AuriemmaFinizia Auriemma
- Miriam ScotiMSMiriam Scoti
- Rocco Di GirolamoRGRocco Di Girolamo
- Massimo Christian D'ALterioMDMassimo Christian D'ALterio
- Giovanni RicciGiovanni Ricci
- Giorgia ZanchinGiorgia Zanchin
- Giuseppe LeoneGLGiuseppe Leone
- 30 July 2019
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Polymer Chemistry
- Vol. 10 (33) , 4593-4603
Abstract
When norbornadiene is polymerized with TiCl 4 /Et 2 AlCl catalytic system, a unique 3,5-poly(norbornadiene) is obtained. This new polymer is able to crystallize notwithstanding the presence of configurational disorder and packing disorder.Keywords
Funding Information
- Università degli Studi di Napoli Federico II
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