Design of New Eco-Cementitious Material Based on Foundry Slag and Lime Sludge

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Abstract
Foundry slag has different characteristics from blast furnace slag, such as its high SiO2 content and low basicity (CaO/SiO2 < 1), which prevent it from being used as a cementitious component. Lime slurry is a waste product with a high CaO content and can be used to increase the basicity of the mixture. The aim of this study is to obtain new supplementary, eco-cementitious material composed of foundry slag and lime sludge. The compositions were designed with binary basicity (molar ratio of CaO/SiO2) ranging from 1.0 to 1.4. Clinker was replaced with the proposed material in the range of 6–34 wt% and the performance of the different cement compositions was tested. The results showed that replacing 20 wt% of clinker with the new eco-cementitious material with binary basicity of 1.2 resulted in cement with the same mechanical strength as the reference cement. The new material reacted with free CaO to generate additional calcium silicate hydrate. The initial setting time of the cement containing the new eco-cementitious material was 240 min, acting as hydration reaction retardant. The technical feature of the new eco-cementitious material allows the use of both wastes in cement composition, contributing to the requirements of circular economy.

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