Direct Synthesis of Organic Azides from Primary Amines with 2‐Azido‐1,3‐dimethylimidazolinium Hexafluorophosphate
- 14 December 2010
- journal article
- research article
- Published by Wiley in European Journal of Organic Chemistry
- Vol. 2011 (3) , 458-462
Abstract
Organic azides were prepared from primary amines in high yields by metal‐free diazo transfer with 2‐azido‐1,3‐dimethylimidazolinium hexafluorophosphate, which is a stable, crystalline solid that is easy to handle.Keywords
This publication has 29 references indexed in Scilit:
- 2-Azido-1,3-dimethylimidazolinium Chloride: An Efficient Diazo Transfer Reagent for 1,3-Dicarbonyl CompoundsSynlett, 2009
- Cu(I)-Catalyzed Huisgen Azide−Alkyne 1,3-Dipolar Cycloaddition Reaction in Nucleoside, Nucleotide, and Oligonucleotide ChemistryChemical Reviews, 2009
- Klick‐Chemie jenseits von metallkatalysierten CycloadditionenAngewandte Chemie, 2009
- An Efficient, Inexpensive, and Shelf-Stable Diazotransfer Reagent: Imidazole-1-sulfonyl Azide HydrochlorideOrganic Letters, 2007
- CuI‐Catalyzed Alkyne–Azide “Click” Cycloadditions from a Mechanistic and Synthetic PerspectiveEuropean Journal of Organic Chemistry, 2005
- Organische Azide – explodierende Vielfalt bei einer einzigartigen SubstanzklasseAngewandte Chemie, 2005
- Die Staudinger‐Ligation – ein Geschenk für die Chemische BiologieAngewandte Chemie, 2004
- Iminophosphoranes: Useful Building Blocks for the Preparation of Nitrogen-Containing HeterocyclesSynthesis, 1994
- Efficient solid phase peptide synthesisInternational Journal of Peptide and Protein Research, 1992
- Azomethine Ylids, Azomethine Imines, and Iminophosphoranes in Organic SynthesesSynthesis, 1973