Stability of metal–metal interactions in transmetallation intermediates based on electronics of bridging arene ligands determined through pyridine titrations

Authors:
Open Access
Publisher website
Google Scholar
Abstract
Herein, we compare the known dinuclear complex [(CNC)(PPh 3 )Pt–Au(PPh 3 )] + ( 2 ) with the newly synthesized [(CNC F )(PPh 3 )Pt–Au(PPh 3 )] + ( 2-F ). We use pyridine titrations to establish the relative thermodynamic stability of 2 vs. 2-F .
Funding Information
  • Boston University

This publication has 48 references indexed in Scilit: