High-sensitivity NO2 fluorescence sensor based on a QDs@Aerogels/SM composite nanofilm

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Abstract
Quantum dots (QDs) exhibit excellent optical and chemical properties, making them advantageous for fluorescence sensing. However, gas sensor using QDs is often hampered by challenges such as gas diffusion and low concentration. This work describes the development of a nitrogen dioxide (NO2) fluorescence gas sensor that utilizes a QDs@Aerogels/SM composite nanofilm containing CdTe QDs modified by reduced glutathione (GSH), silica microspheres (SMs), and silica aerogel. The SM and porous aerogels create a uniform porous structure that enhances the distribution of QDs. Compared to the pure QDs film, the QDs@Aerogels/SM composite film exhibits enhanced fluorescence intensity. The porous structure promotes the adsorption of NO2, which improves the detection sensitivity. The QDs@Aerogels/SM composite film was applied in a portable gas sensor. The sensor demonstrates a good linear response to NO2 gas in the range of 0–10 ppm, with an ultra-low detection limit of 0.096 ppm and high selectivity. The uniform distribution of aerogel and SM enhances the stability of the composite nanofilm, and the fluorescence of the films remains virtually unchanged over a period of 60 days which ensures its optimal performance over extended periods of use. The fluorescent NO2 sensor demonstrated selective and sensitive quenching upon exposure to NO2, making it ideal for environmental monitoring and further applications.
Funding Information
  • National Natural Science Foundation of China (11874157, 11964032)
  • Science and Technology Program of Guangzhou (2019050001)
  • Science and Technology Planning Project of Guangdong Province (2019A1515011014)
  • Key Project of Education Department of Guangdong Province (2018KZDXM025, 2019GKTSCX009)
  • Open Fund of Guangdong Provincial Key Laboratory of Information Photonics Technology (GKPT20-12)

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