Nano carbon sphere modified CoAl 2 O 4 –CdS Z-scheme heterojunctions: broad-spectrum absorption enhanced photocatalytic hydrogen evolution

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Abstract
The 20% CAO–CdS–CS showed that the average hydrogen evolution rate over 5 hours for 20% CAO–CdS–CS was 43.1 mmol g −1 h −1 . Based on XPS and DFT characterization analyses, it is inferred that a Z-scheme heterojunction forms between CoAl 2 O 4 and CdS.

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