Long-range coupling in a mixed-valence diruthenium complexes containing bis-terpyridine ligands of various lengths as bridges
Authors:
- Jean-Paul CollinJCJean-Paul Collin
- Philippe LainéPhilippe Lainé
- Jean-Pierre LaunayJLJean-Pierre Launay
- Jean-Pierre SauvageJSJean-Pierre Sauvage
- Angélique SourASAngélique Sour
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 434-435
Abstract
Dinuclear ruthenium(II) complexes have been prepared which contain back-to-back bis-terpyridine ligands of various lengths (Ru ⋯ Ru distances between 7 and 20 Å) as bridges; significant electronic coupling is observed in mixed-valence states, even for the system with the longest separation.Keywords
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