exoALMA. XXIV. Formaldehyde Emission in Protoplanetary Disks of exoALMA Compared with Their Properties and Dynamical State

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Abstract
The presence of asymmetries and substructures in protoplanetary disks, revealed by both dust and gas emission, highlights the potential interplay and the broader connection between chemistry and dynamics in disk evolution. We explore multiple relationships using the nonparametric Kendall- τ correlation to examine formaldehyde (H 2 CO) emission with relation to stellar and disk properties for a subset of disks from the exoALMA sample. We also retrieve the H 2 CO column density and excitation temperature using four transitions, measured in radial bins of 100 au, and quantify the level of asymmetry in the resolved peak intensity of the H 2 CO emission. From our correlation analysis, we find no correlations with sufficient statistical significance. However, we identify tentative relationships that can be tested with larger samples. In particular, we report a proposed correlation (2.1 σ ) between stellar effective temperature and the formaldehyde excitation conditions, suggesting that, to first order, the central star dominates the nature of the H 2 CO emission over possible dynamical asymmetries traced by dust. Although a correlation with the stellar luminosity was also expected, a larger sample is required to confirm or refute this trend. A possible correlation with spectral type, together with the broad range of H 2 CO excitation temperatures within the inner 100 au of the studied disks, hint at possible multiple chemical formation pathways for H 2 CO, including both gas-phase reactions and ice-surface chemistry on dust grains.
Funding Information
  • EC ∣ European Research Council (01076613)
  • Ministero dell'Università e della Ricerca (2022YP5ACE.)
  • Agencia Nacional de Investigación y Desarrollo (FB210003)
  • EC ∣ Horizon Europe ∣ Excellent Science ∣ HORIZON EUROPE European Research Council (101002188)
  • National Science Foundation (2511673)
  • National Science Foundation (2407679)
  • EC ∣ Horizon Europe ∣ Excellent Science ∣ HORIZON EUROPE Marie Sklodowska-Curie Actions (823823)
  • UKRI ∣ Science and Technology Facilities Council (ST/W004119/1)
  • Australian Research Council (FT170100040)
  • Australian Research Council (DP18010423)
  • Australian Research Council (DP220103767)
  • Australian Research Council (DP240103290)

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