Metallo-Carbohedrenes [M 8 C 12 + (M = V, Zr, Hf, and Ti)]: A Class of Stable Molecular Cluster Ions

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Abstract
Findings of magic peaks corresponding to M 8 C 12 + (M = V, Zr, and Hf) formed from reactions of the respective metals with various small hydrocarbons, in conjunction with recent findings for the titanium system, establish metallo-carbohedrenes as a stable general class of molecular cluster ions. A dodecahedral structure of T h point symmetry accounts for the stability of these ionic clusters.

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