GLYCERIDE SYNTHESIS: I. SYNTHESIS OF SYMMETRICAL DIGLYCERIDES FROM DIHYDROXY ACETONE AND ALLYL ALCOHOL
Authors:
- P. J. BarryPBP. J. Barry
- B. M. CraigBCB. M. Craig
- 1 April 1955
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 33 (4) , 716-721
Abstract
1,3-Distearoxy acetone and 1,3-dipalmitoxy acetone were prepared by interesterification of the methyl esters of the fatty acids with 1,3-dipropionoxy acetone diethyl mercaptal. The 1,3-diglycerides were obtained by hydrogenation of the ketone group. Allyl tetrahydropyranyl ether was oxidized to 1-tetra-hydropyranyl glycerol which was acetylated and interesterified with methyl esters of fatty acids to produce 1,3-diglycerides.Keywords
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