Enthalpy and entropy changes for formation of nickel(II) complexes with some C-alkylethylenediamines

Authors:
  • HPHkj Powell
    Hkj Powell
  • NCNf Curtis
    Nf Curtis
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Abstract
Enthalpy and entropy data are reported for the formation of nickel(II) complexes with the ethylenediamine homologues propane-1,2-diamine and 2-methyl-propane-1,2-diamine. Trends in ?H values are related to ligand basicity and to solvation of the complex ions.