Crosslinking mechanism of an anhydride‐cured epoxy resin as studied by fourier transform infrared spectroscopy
Authors:
- 1 February 1981
- journal article
- research article
- Published by Wiley in Journal of Polymer Science: Polymer Chemistry Edition
- Vol. 19 (2) , 549-570
Abstract
Fourier transform infrared spectra, including absorbance difference spectra, are presented which indicate that the accepted mechanism of tertiary amine‐catalyzed copolymerization of cyclic anhydrides and epoxy resins requires modification. Results also show that the kinetic model is complicated by the lack of steady‐state concentrations of the active species. The effect of silica filler and silane coupling agents on the reaction are also examined.Keywords
This publication has 41 references indexed in Scilit:
- The curing of an epoxy resin as followed by carbon-13 NMR spectroscopyJournal of Applied Polymer Science, 1976
- Base-induced rearrangement of epoxides. V. Phenyl-substituted epoxidesThe Journal of Organic Chemistry, 1972
- Kinetics of epoxy cure: 2. The system bisphenol-A diglycidyl ether/polyamidePolymer, 1972
- Study of epoxy compounds. Part I. Curing reactions of epoxy resin and acid anhydride with amine and alcohol as catalystJournal of Applied Polymer Science, 1963
- Polyesters from expoxides and anhydridesJournal of Polymer Science, 1960
- The Nature of Hydrogen Bonded Ion-Pairs: The Reaction of Pyridine and Carboxylic Acids in ChloroformJournal of the American Chemical Society, 1956
- The curing mechanism of epoxy resinsJournal of Chemical Technology & Biotechnology, 1956
- Acid-Base Reactions in Non-dissociating Solvents n-Butylamine and Acetic Acid in Carbon Tetrachloride and ChloroformJournal of the American Chemical Society, 1955
- Acid-Base Reactions in Non-dissociating Solvents. Acetic Acid and Triethylamine in Carbon Tetrachloride and ChloroformJournal of the American Chemical Society, 1954
- The Reactions of Some Organometallic Compounds with Cyclohexene Oxide1Journal of the American Chemical Society, 1952