Online Monitoring of Heterogeneous Polymerizations in Supercritical Carbon Dioxide by Raman Spectroscopy
- 14 June 2012
- journal article
- research article
- Published by Wiley in Chemphyschem
- Vol. 13 (11) , 2666-2670
Abstract
A novel setup is described to monitor the kinetics of homogeneous and heterogeneous reactions online using Raman spectroscopy under high pressure. The arrangement is based on a high‐pressure reactor equipped with a sapphire window in combination with a mobile probe that allows the collection of the back‐scattered Raman signal at 360°.Keywords
This publication has 23 references indexed in Scilit:
- 1H ,1H ,2H ,2H -Perfluorodecyl-Acrylate-Containing Block Copolymers from ARGET ATRPMacromolecular Chemistry and Physics, 2010
- In Line Spectroscopic Investigation of Fluorinated Copolymer Synthesis in Supercritical Carbon DioxideMacromolecular Symposia, 2010
- Solvation Structures of cis- and trans-1,2-Dichloroethylene in Supercritical CO2 Investigated by Raman Spectroscopy and Attractive Energy CalculationsThe Journal of Physical Chemistry B, 2009
- Kinetic Study of Hydrodechlorination of Chlorobiphenyl with Polymer-Stabilized Palladium Nanoparticles in Supercritical Carbon DioxideThe Journal of Physical Chemistry A, 2009
- Controlled/living heterogeneous radical polymerization in supercritical carbon dioxideJournal of Polymer Science Part A: Polymer Chemistry, 2009
- Difference of Solute−Solvent Interactions of cis- and trans-1,2-Dichloroethylene in Supercritical CO2 Investigated by Raman SpectroscopyThe Journal of Physical Chemistry B, 2008
- Experimental spectroscopic high-temperature high-pressure techniques for studying liquid and supercritical fluidsVibrational Spectroscopy, 2004
- Kinetics of the Early Stage of Dispersion Polymerization in Supercritical CO2 As Monitored by Turbidimetry. 2. Particle Formation and Locus of PolymerizationMacromolecules, 2002
- Schwingungsspektroskopie in überkritischen fluiden Phasen: von der Analytik bis zur SynthesechemieAngewandte Chemie, 1995
- Raman Studies of Molecular Potential Energy Surface Changes in Supercritical Fluids1992