Design and modeling of diazinon degradation in hydrous matrix by Ni-doped ZnO nanorods under ultrasonic irradiation: process optimization using RSM (CCD), kinetic study, reaction pathway, mineralization, and toxicity assessment

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Abstract
In first, the Ni-doped ZnO nanorods used as an appeal sonocatalyst was synthesized through co-precipitation method. Afterwards, the crystalline structure, functional groups, surface morphology, and elemental composition were characterized by a set of analysis. Removal of diazinon ((DZ) as a renowned pesticide) was investigated using sonocatalytic performance of US/Ni-doped ZnO system. In this empirical study, response surface methodology (RSM) based central composite design (CCD) was applied for optimization of operational factors. Under the optimum conditions such as initial pH = 5, initial DZ concentration = 15 mg L−1, sonocatalyst dosage = 1 g L−1, and in the presence of organic compounds (oxalic acid, humic acid, and folic acid) = 3 mg L−1, the sonocatalytic degradation of DZ after 15 min was 82.29%. The F-value (6.64) and P-value (< 0.0001) for DZ degradation in the quadratic model imply the proposed model was significant. A-factor (pH) considers as a prominent factor owing to having the highest F-value. In addition, the sonocatalytic data in this study exhibited valid fitting for the first order kinetic model (R2 > 0.98). After six consecutive cycles, the Ni-doped ZnO nanorods could be recyclable for sonocatalytic degradation of DZ. The five main compounds produced during the US/Ni-doped ZnO embracing 2-isopropyl-6-methyl-4-pyrimidinol (IMP), diethyl phosphonate, diazoxon, hydroxyldiazinon, and diazinon methyl ketone are formed in the path of DZ degradation. OFAT style also revealed 99.99% of DZ degradation with 73.26% of mineralization rate in optimum status. The Ni-doped ZnO presented agreeable sonocatalytic facility in the refinement of real water and wastewater matrix. Finally, the results of toxicity evaluation (Daphnia magna) in the sonocatalytic degradation of DZ (by US/Ni-doped ZnO system) showed that the toxicity of the DZ solution lessened under US waves (LC50 and TU 48 h equal to 36.472 and 2.741 volume percent, respectively).

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