Intensely Luminescent Gold(I)−Silver(I) Cluster with Hypercoordinated Carbon
Authors:
- 3 November 2009
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 131 (46) , 16634-16635
Abstract
Intense solution and solid state phosphorescence was observed on a novel photostable gold(I)−silver(I) cluster with hypercoordinated carbon, [Au6Ag2(C)(dppy)6](BF4)4, which has a core structure of a hexagold(I) octahedron with two silver(I) atoms capping on a pair of its faces; the incorporation of silver atoms enhances the rigidity and integrity of the cluster.Keywords
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