Epoxide polymers: Synthesis, stereochemistry, structure, and mechanism

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Abstract
Epoxide polymerization studies have yielded technically important catalysts and polymers. The polymers were studied by cleaving them with Group IA organometallics to monomer, dimer, and trimer glycol fragments. The identification of these glycol fragments has established that the crystalline polymers from the cis‐ and trans‐2,3‐epoxybutanes are respectively racemic and meso‐diisotactic and that the amorphous polymer from the cis‐oxide is disyndiotactic. These studies also showed that the amorphous fraction from propylene oxide polymerization with coordination catalysts contains substantial head‐to‐head and tail‐to‐tail segments. This work has led to a much better understanding of the mechanism of epoxide polymerization. These facts were established: (1) epoxides polymerize with inversion of configuration of the ring‐opening carbon atom; (2) monosubstituted epoxides polymerize largely by attack on the primary carbon with a coordination catalyst; and (3) two or more metal atoms must be involved in the coordination polymerization of epoxides.

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