Improved film growth and flatband voltage control of ALD HfO/sub 2/ and Hf-Al-O with n/sup +/ poly-Si gates using chemical oxides and optimized post-annealing

Authors:
  • BBB. Brijs
    B. Brijs
  • RDR.B. van Dover
    R.B. van Dover
  • AKA. Kornblit
    A. Kornblit
  • TGT. Gustafsson
    T. Gustafsson
  • EGE. Garfunkel
    E. Garfunkel
  • SHS. Hillenius
    S. Hillenius

Abstract
We demonstrate for the first time that chemical oxide underlayers /spl sim/5 /spl Aring/ thick provide improved growth and flatband voltage control of ALD HfO/sub 2/ films compared to thermal oxides. Optimized annealing conditions are shown to greatly reduce both fixed charge and interfacial oxide growth in the high-/spl kappa/ stacks. Extremely small flatband voltage shifts of <30 mV are achieved, corresponding to a very low fixed charge of Q/sub f//spl sim/2E11/cm/sup 2/.

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