ortho‐Selective Phenol‐Coupling Reaction by Anodic Treatment on Boron‐Doped Diamond Electrode Using Fluorinated Alcohols
- 12 February 2009
- journal article
- research article
- Published by Wiley in Chemistry – A European Journal
- Vol. 15 (10) , 2273-2277
Abstract
Enlarged scope by fluorinated mediators: Oxyl radicals are easily formed on boron‐doped diamond (BDD) electrodes and can be exploited for the ortho‐selective coupling to the corresponding biphenols (see scheme). At partial conversion, a clean transformation is achieved that can be applied to electron‐rich as well as fluorinated phenols. magnified imageKeywords
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