Catalytic enantioselective assembly of complex molecules containing embedded quaternary stereogenic centres from simple anisidine derivatives
- 18 May 2011
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Science
- Vol. 2 (8) , 1487-1490
Abstract
Here we report an electrophile-triggered, secondary amine-catalyzed, enantioselective dearomatisation process that converts simple planar anisidine derivatives into complex tricyclic structures containing a quaternary stereogenic centre embedded within a densely functionalised molecule.Keywords
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