Radical Cation Salts of Simple Arenes—A New Family of “Organic Metals”
Authors:
- 1 November 1980
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition
- Vol. 19 (11) , 912-919
Abstract
“Organic metals” from naphthalene, fluoroanthene, perylene, etc. in the form of the radical cation salts [arene2]⊙⊕X⊖ (X = PF6, AsF6, SbF6, BF4) can be generated as shiny black crystals by anodic oxidation of arenes in the presence of the anions. Species of this type were previously limited to heterocycles and compounds containing hetero atoms.Keywords
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