Tris(2,2′-bipyridyl-κ2N,N′)copper(II) sulfate 7.5-hydrate
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Open Access
- 8 January 2009
- journal article
- other
- Published by International Union of Crystallography (IUCr) in Acta Crystallographica Section E Structure Reports Online
- Vol. 65 (2) , m129-m130
Abstract
The title compound, [Cu(C(10)H(8)N(2))(3)]SO(4)·7.5H(2)O, is a six-coordinate copper(II) complex with a slightly elongated octa-hedral coordination geometry. The pyridyl rings of the three bipyridyl ligands are not coplanar, making dihedral angels of 9.5 (5), 5.2 (4) and 5.8 (5)°. In the crystal, several O-H⋯O and C-H⋯O hydrogen-bonding inter-actions are observed due to the existance of a large number of water mol-ecules and the sulfate dianions.Keywords
This publication has 8 references indexed in Scilit:
- A short history of SHELXActa Crystallographica Section A Foundations of Crystallography, 2007
- Tris(2,2′-bipyridine-κ2N,N′)copper(II) bis(tetrafluoridoborate)Acta Crystallographica Section E Structure Reports Online, 2007
- Tris(2,2′-bipyridyl-κ2 N,N′)copper(II) hexafluoridophosphateActa Crystallographica Section E Structure Reports Online, 2007
- Structural systematics of the [Cu(chelate)3][Y]2series. An interesting crystallographic structural insight involving vibronic coupling and the Jahn–Teller effect (JTE). The syntheses and low temperature crystal structures of tris(2,2′bipyridyl)copper(ii) tetraphenylborate and tris(2,2′bipyridyl)zinc(ii) tetraphenylborateDalton Transactions, 2005
- Silver(I) Assisted Metal Exchange Reaction. A Generalized Synthesis of Tris-Chelated Copper(II) Complexes of Neutral N,N-DonorsInorganic Chemistry, 1998
- X-ray crystal structure of Cu(bipy)3(ClO4)2Polyhedron, 1991
- The crystal structure of tris(2,2'-bipyridyl)nickel(II) sulphate hydrate, [Ni(C10H8N2)3]SO4.7.5H2OActa Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 1976
- Crystal and molecular structure of tris-(2,2′-bipyridyl)copper(II) perchlorateJ. Chem. Soc., Dalton Trans., 1972