Adaptable Hetero Diels–Alder Networks for Fast Self‐Healing under Mild Conditions
- 21 March 2014
- journal article
- research article
- Published by Wiley in Advanced Materials
- Vol. 26 (21) , 3561-3566
Abstract
A novel adaptable network based on the reversible hetero Diels–Alder reaction of a cyanodithioester and cyclopentadiene is presented. Reversible between 50–120 °C, the adjustable and self‐healing features of the network are evidenced via temperature dependent rheology experiments and repetitive tensile tests whereas the network's chemical structure is explored by temperature dependent 1H MAS‐NMR spectroscopy.Keywords
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