Evaluating Classifications of Extremely Metal-poor Candidates Selected from Gaia XP Spectra

Extremely metal-poor stars are intrinsically rare, but emerging methods exist to accurately classify them from all-sky Gaia XP low-resolution spectra. To assess their overall accuracy for targeting metal-poor stars, we present a high-resolution spectroscopic followup of 75 very metal-poor candidates selected from the catalog by R. Andrae, V. Chandra, and H. W. Rix. We discover 2 new extremely metal-poor ($\rm{[Fe / H]}<-3$) stars and 20 new very metal-poor ($\rm{[Fe/H]} < -2$) stars. Abundances of up to 22 elements are derived from 1D local thermodynamic equilibrium analysis and kinematic parameters are derived using Gaia astrometry and spectroscopic radial velocities. The chemodynamical properties are mostly consistent with expectations for halo stars, but we discover an Mg-enhanced CEMP star ($\mathrm{[Mg/Fe]} = 0.89$) and an Mg-poor star from an accreted ultra-faint dwarf galaxy. The Gaia XP metallicity estimates are consistent with our $\rm{[Fe/H]}$ measurements down to $\rm{[Fe/H]}\sim -3.0$, but estimates worsen in highly extincted regions. We find that 4 other XP-based metallicity catalogs succeed in mitigating contaminants and can also classify metal-poor stars robustly to $\rm{[Fe/H]}\sim -3.0$. Our results demonstrate the utility of Gaia XP spectra for identifying the most metal-poor stars across the Galaxy.