Testing the extraction of past seawater Nd isotopic composition from North Atlantic deep sea sediments and foraminifera
Authors:
- 30 September 2011
- journal article
- Published by American Geophysical Union (AGU) in Geochemistry, Geophysics, Geosystems
- Vol. 12 (9)
Abstract
Neodymium isotopes provide a paleoceanographic proxy for past deep water circulation and local weathering changes and have been measured on various authigenic marine sediment components, including fish teeth, ferromanganese oxides extracted by acid‐reductive leaching, cleaned foraminifera, and foraminifera with Fe‐Mn oxide coatings. Here we compare Nd isotopic measurements obtained from ferromanganese oxides leached from bulk sediments and planktonic foraminifera, as well as from oxidatively‐reductively cleaned foraminiferal shells from sediment cores in the North Atlantic. Sedimentary volcanic ash contributes a significant fraction of the Nd when the ferro‐manganese (Fe‐Mn) oxide coatings are leached from bulk sediments. Reductive leachates of marine sediments from North Atlantic core tops near Iceland, or directly downstream from Iceland‐Scotland Overflow Waters, record ɛNd values that are significantly higher than seawater, indicating that volcanic material is easily leached by acid‐reductive methods. The ɛNd values from sites more distal to Iceland are similar to modern seawater values, showing little contamination from Iceland‐derived volcanogenic material. In all comparisons, core top planktonic foraminifera ɛNd values more closely approximate modern deep seawater than the bulk sediment reductive leached value suggesting that the foraminifera provide a route toward quantifying the Nd isotopic signature of deep North Atlantic water masses.Keywords
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