Enantioselective Synthesis of (R)-α-(p-Nitroaryl)prolines via Oxidative Nucleophilic Substitution of Hydrogen in Nitroarenes

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Abstract
Optically pure (R)-α-(p-nitroaryl)prolines are synthesized via oxidative nucleophilic substitution of hydrogen in nitroarenes using chiral carbanion of l-proline protected as N,O-acetal of pivalaldehyde.