The photoelectron and far-ultraviolet absorption spectra of simple oximes

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Abstract
The HeI photoelectron and far ultraviolet absorption spectra of formaldoxime (CH2=N–OH) and three other simple nonconjugated oximes are reported and compared to those of simple imines. Contrary to imines the lowest ionization potential seems to be related to the π orbital although this assignment must be considered tentative. In the uv spectrum the π*←n, π*←π and 3s←π bands are readily identified.

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