Decomposition and Cell Failure Mechanisms in Lead Halide Perovskite Solar Cells
- 9 August 2016
- journal article
- research article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 56 (1) , 92-101
Abstract
Perovskite solar cells have experienced a remarkably rapid rise in power conversion efficiencies, with state-of-the-art devices now competing with multicrystalline silicon and thin-film cadmium telluride in terms of efficiency. Unfortunately, the lead halide perovskite absorbers suffer from a lack of chemical stability and decompose in response to a variety of environmental stimuli. In this Forum Article, we provide a brief overview of the decomposition mechanisms in lead halide perovskite thin films, as well as the processes contributing to cell failure in finished devices. We finish by briefly surveying recent efforts to extend the device lifetime. Ultimately, if perovskite solar cells can be made stable, they will be an exciting, highly complementary addition to existing photovoltaic technologies.Keywords
Funding Information
- Canada Research Chairs
- Natural Sciences and Engineering Research Council of Canada
This publication has 81 references indexed in Scilit:
- Efficient planar heterojunction perovskite solar cells by vapour depositionNature, 2013
- Sequential deposition as a route to high-performance perovskite-sensitized solar cellsNature, 2013
- Reporting Performance in Organic Photovoltaic DevicesACS Nano, 2013
- Chemical Management for Colorful, Efficient, and Stable Inorganic–Organic Hybrid Nanostructured Solar CellsNano Letters, 2013
- Synthesis and crystal chemistry of the hybrid perovskite (CH3NH3)PbI3 for solid-state sensitised solar cell applicationsJournal of Materials Chemistry A, 2013
- Energy Balance of the Global Photovoltaic (PV) Industry - Is the PV Industry a Net Electricity Producer?Environmental Science & Technology, 2013
- Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide PerovskitesScience, 2012
- Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic CellsJournal of the American Chemical Society, 2009
- Stability/degradation of polymer solar cellsSolar Energy Materials and Solar Cells, 2008
- Alkylammonium lead halides. Part 1. Isolated PbI64− ions in (CH3NH3)4PbI6•2H2OCanadian Journal of Chemistry, 1987